Authors : Mohammad Tawkir and S.A. Iqbal
Page Nos : 154-164
Description :
Gliclazide and Glimeperide complexes of Fe(III) was synthesized . Metal-Ligand ratio Calculated by Conductometric Titration using Monovariation method which was further confirmed by Job’s Method of continuous variation.Elemental analysis confirmed the complexes found to have formula (C15H21N3O3S)2Fe•2H2O, (C24H34N4O5S)2Fe•2H2O.The complexes are assigned ionic confirmed by high molar conductance value..Geometry of complexes assigned Octahedral structure (Scheme-I and Scheme-II) has been discussed and suggested upon Elemental analysis and I.R.,X-Ray diffraction powder method.Thermal decomposition has been studied using Thermogravimetric (TGA) .Kinetic parameters were evaluated by Freeman-Carroll and Sharp-Wentworth method.
